Ta có \({V_{C.A'B'C'}} = \frac{1}{3}d\left( {C,\left( {A'B'C'} \right)} \right).{S_{A'B'C'}} = \frac{1}{3}{V_{ABC.A'B'C'}} = \frac{2}{3}\)

Suy ra \({V_{C.ABB'A'}} = {V_{ABC.A'B'C'}} - {V_{C.A'B'C'}} = 2 - \frac{2}{3} = \frac{4}{3}\)

Ta thấy \(ABNM\) là hình thang nên

\(\begin{array}{l}{S_{ABNM}} = \frac{{\left( {AM + BN} \right)d\left( {BN;AM} \right)}}{2} = \frac{{\left( {\frac{{AA'}}{2} + \frac{{BB'}}{3}} \right).d\left( {BB',AA'} \right)}}{2}\\ = \frac{{\left( {\frac{{AA'}}{2} + \frac{{AA'}}{3}} \right).d\left( {BB',AA'} \right)}}{2} = \frac{5}{{12}}AA'.d\left( {BB',AA'} \right)\end{array}\)

Mà \({S_{ABB'A'}} = AA'.d\left( {AA',BB'} \right) \Rightarrow {S_{ABNM}} = \frac{5}{{12}}.{S_{ABB'A'}}\)

 \(\begin{array}{l} \Rightarrow {V_{C.ABNM}} = \frac{1}{3}d\left( {C,\left( {ABNM} \right)} \right).{S_{ABNM}} = \frac{1}{3}d\left( {C,\left( {ABB'A'} \right)} \right).\frac{5}{{12}}.{S_{ABB'A'}}\\ = \frac{5}{{12}}.\frac{1}{3}d\left( {C,\left( {ABB'A'} \right)} \right).{S_{ABB'A'}} = \frac{5}{{12}}.{V_{CABB'A'}}.\end{array}\)

Mà \({V_{C.ABB'A'}} = \frac{4}{3}\left( {cmt} \right) \Rightarrow {V_{C.ABNM}} = \frac{5}{{12}}.\frac{4}{3} = \frac{5}{9}.\)

Suy ra \({V_{CC'B'NMA'}} = {V_{ABC.A'B'C'}} - {V_{C.ABNM}} = 2 - \frac{5}{9} = \frac{{13}}{9}.\)

Ta có \(A'M//CC' \Rightarrow \frac{{PA'}}{{PC'}} = \frac{{A'M}}{{CC'}} = \frac{1}{2} \Rightarrow PA' = \frac{1}{2}PC' = A'C' \Rightarrow PC' = 2A'C'\)

Và \(B'N//CC' \Rightarrow \frac{{B'N}}{{CC'}} = \frac{{QB'}}{{QC'}} = \frac{2}{3} \Rightarrow QC' = 3B'C'\)

Mà \({S_{A'B'C'}} = \frac{1}{2}C'A'.C'B'\sin C'\) 

\( \Rightarrow {S_{C'PQ}} = \frac{1}{2}C'P.C'Q.\sin C' = \frac{1}{2}.2.A'C'.3B'C'\sin C = 6.\left( {\frac{1}{2}A'C'.B'C'\sin C} \right) = 6{S_{A'B'C'}}\)

Ta có: \({V_{C.C'PQ}} = \frac{1}{3}d\left( {C;\left( {A'B'C'} \right)} \right).{S_{C'PQ}} = \frac{1}{3}d\left( {C;\left( {A'B'C'} \right)} \right).6{S_{C'A'B'}} = 6.{V_{C.A'B'C'}} = 6.\frac{2}{3} = 4.\)

Từ đó \({V_{A'MPB'NQ}} = {V_{C.C'PQ}} - {V_{CC'B'NMA'}} = 4 - \frac{{13}}{9} = \frac{{23}}{9}\).

Chọn B.